Thermochromic Polymers

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Thermochromic foils and injection molded plastics




Thermoplastics are non-crosslinked polymers. Their central feature is that they are moldable. Typical examples of thermoplastic polymers are Polyolefines, Polyesters, Polyamides, Polyacrylates and Polyvinylchloride. Most of these polymers are stable in the molten state. Thus they can be treated by extrusion technology or injection molding. During these processes high temperatures and strong mechanical stresses are applied. Thermochromic pigments developed in our laboratory can be already added to the raw polymer before the extrusion process. In this way, a technology compatible production of thermochromic foils and injection molded plastics in which the thermochromic dye is evenly distributed in the total polymer volume could be demonstrated for the first time. Switching temperatures from 0°C to 70°C and a variety of colors are available at the moment, whereby the color changes can take place reversible or irreversible.

A vacuum deposition of transparent electrodes on the thermochromic polymer material in an ultra high vacuum of about 10-7 Torr enables a hybrid active-passive color switching. Thermal or electron beam techniques have been successfully used for the preparation of the electrodes.